Oh yeah, noobs are limited to Rock, Paper, Scissors. All advanced choices therefore must have either a 1/3 or a 2/3 chance of beating a noob. By dueling noobs who clearly do not have enough points to have unlocked any RPS choices other than the basic three, and by picking an "advanced" RPS option that beats 2/3 of the basic three, you can increase your odds to 66.7%. Factoring in deviation and the occasional duel against a more experienced site member, this explains Briar_Rose's win ratio of 64.8%.
Also, looking at Chanbot's dueling record, and the variation of his win rate over time, I think the odds of beating cysid are probably exactly 50%. The variation in win rate (5-8 losses in succession) is by no means abnormal.